| comments Henry, I will do the math and write another reply to this thread on the specifics of dechlorination with sodium thiosulfate. Right now, I just want to rant on this subject for a few minutes instead, saying those things that need to be said to orient us on this subject.
On the Water Gardening board, the most prominent posters often state there is no need for dechlorination with water exchanges, and most of them openly write on that board how their fish thrive through large water changes without dechlorination. One specific poster, who puts up pictures of their fish every week of the year on that board, even states they exchange ~ 30% of the water weekly in the pond system during Summer months without dechlorination, using city water, making a small water exchange every day without dechlorination. So the practice is not isolated to the mountain folk of "West By God Virginia" "Country Roads" territory. After interacting with those particular folks on the Water Gardening board for a year or so, I gave up trying to persuade them to use dechlorinator, and instead cautioned them that changing that much water without dechlorination should only be done in Summer months when there is enough DOC to "eat" the chlorine immediately.
The process of DOC "eating" chlorine is the same process as DOC "eating" a potassium permanganate charge. Surely some of you have used potassium permanganate in a "dirty" pond somewhere in your ponding experience to see a significant PP charge dissappear in less than 15 minutes after it is charged. That is because the water was dirty enough with enough DOC content for the potassium permanganate to rapidly be used up. The same thing happens to chlorine. If the ORP (Oxidation Reduction Potential) of the pond measures below 200 millivolts, adding fresh water without dechlorinator is unlikely to kill the fish since the chlorine or chloramine will be almost immediately consumed. But if it is a clean pond with an ORP reading above 325, adding a significant water exchange using city water is very likely to either kill the fish or do real harm to the gills. Fresh tap water usually is an ORP reading ~ 500 or so from the chlorine or chloramine oxidizer present to provide the oxidation potential. My swimming pool water routinely runs an ORP reading of ~700 millivolts from the 2 to 5 ppm chlorine content I maintain in the swimming pool. Any ORP reading in excess of 500 is likely to kill the fish if it lasts for more than a few hours.
I was called to one local pond a couple of years ago with dying fish. I tested all the "normal" water parameters, and everything checked perfectly. I checked the fish, no parasites I could find. So I started asking questions about the history of the pond. The pond had been emptied for the Winter after all the fish had been killed the previous fall, the gardener for the estate had left a hose running in the pond overflowing it for 24 hours without dechlorinator. The pond had been filled with city water in the Spring, no dechlorinator. The filter system had been turned on, which consisted of a large fountain lava rock trickle tower filter in the middle of the pond with recirculation from a submersible pump. After running the water for three weeks through the fountain with high aeration, it was assumed the chlorine was gone and excess koi from the son's pond had been added (the son of the lady lives a few houses down the street from me). The fish started dying after about a week in the pond, no fresh water had been added. So I measured for chlorine content and found a reading of 1 ppm chlorine residual after a months recirculation, the same as fresh city water. The problem was that the pond started sparkling clean, no plants, nothing to "eat" the chlorine. So after a month of aeration, sunlight, and so on, the chlorine was never reacted away, and slowly killed some of the fish. I added dechlorinator, no more fish died.
Likewise, the chlorine in my swimming pool is stable for weeks to months in the Spring or late Fall when no one is swimming in it, and no leaves are falling into it, but the swimming pool needs frequent chlorine additions when the leaf fall is high creating DOC to eat the chlorine content of the water. Likewise, my outdoor koi pond directly under the leaf fall of a large oak tree needs frequent low level (0.2 PPPM!) PP treatments to eat the DOC content in the high leaf fall season to maintain high water quality, but runs ORP readings in the 300 to 400 range without PP treatment the rest of the year. Chlorine and PP are the same chemical and the same effect on the water and the fish, both are strong oxidizers which react immediately with significant DOC content.
There are several points to my post here:
1. If there is nothing for the chlorine (or PP!) to react with, it will be there indefinitely to kill the fish. Neither sunlight nor air will have a significant effect on the chlorine content.
2. Most ponds of "newbies" and "water gardeners" are dirty enough to use up the chlorine in city water in minutes to get by without dechlorination.
3. The "newbies" and "water gardeners" do not understand what they are doing and how it works sufficiently to avoid killing all their fish eventually. This is GOOD for folks who sell fish, and BAD for those of us who are trying to educate them that those practices can be dangerous.
4. Don't waste your breath and typing skills trying to get most of these "water gardening" folks to "do it differently", all you will normally get is hostility from most of them when you try to educate them to the possible errors of their routine practices. Kind of like trying to say some of the practices at USA koi shows should be rethought in the middle of KHV spreading around.....keep it to yourself, no one wants to hear anything they do could be improved.....LOL |