As toxins build up???? We are taking about koi ponds right?
Really there seems to be a disconnect here-- let me try again---
In an aging body of water, the microbial community shifts from one group of dominators to another. In a badly kept water garden this is a shift from mineralization -- nitrification To nitrification --- denitrification. Again, no poison needed. eventually even green water will give way to other , more effective anaerobic species.
Maintenance in a koi pond keeps an environment 'forever young' in terms of a otherwise natural progression. The idea that bacteria is 'poisoning the enemy' is way to 'looking for the complicated and the exotic' when the obvious will do!
The obvious explaination of excess organic is that the gas content is changing. This favors species that thrive on eutrophication systems and environments. In other words, as the environment changes it favors some species over others.
looking at this in reverse, I can change an environment and make green water go away. Am I telling the bacteria to stop that poisoning and leave that algae alone? NO, I'm bringing the balance back to the system by favoring bacteria over unicellular algae- This is exactly what happens in all cases of new pond syndrome.
JR