You've already been given some very good advice, but I'll go ahead and chime in anyway.
I think you underestimate not only the knowledge base of the people who have responded to you, but also their enjoyment of their fish as pets, not just trophies. There are folks around here who go swimming with their fish, so your "People that raise showdogs probably don't get that" notion is way off track.
Your ph levels are fine. Damn near ideal, so that has nothing to do with the PP dosage problems. You mention that your water is hard, but hard is a relative term. What are you Kh and Gh readings? Assuming you have a rocky, gravel bottom pond it is likely somewhat on the hard side by virtue of mineralization of the gravel into the water. The good news is that high Gh has nothing to do with pp dosage. PP is an organic oxidizer, and rocks are inorganic as are any minerals in your water supply.
PP does not harm plants even in massive doses and does not oxidize dirt, so nuking your plants separately will not harm them.
So why IS your pp dosage only lasting 1/2 hr after so many doses??? Because it is very slowly eating away at the mulm in the bottom layer by layer. Parasites are likely living and breeding down there in the muck, and with each dosage of pp you are killing off 1 very thin layer of mulm at a time, which is being quickly replaced by fresh fish poop on the somewhat cleaner top layer. Getting all the crap out of the bottom of the pond is going to take a very long time as it appears you haven't cleaned the bottom in quite a while.
You are correct in stating that you only have one sick fish and 5 healthy ones. You forgot that you also have one dead one too. The first one was the canary in the coal mine. 1 down, 6 to go. The sick one is the next weakest sister, soon to be 2 down, 5 to go. And so it will go until you take it from those who already know what you don't want to hear and fix the problem you refuse to admit you've had all along.