| "CARBONATE HARDNESS Carbonate hardness (KH) is the measure of bicarbonate (HCO3-) and carbonate (CO3--) ions in the water. In freshwater aquariums of neutral pH, bicarbonate ions predominate and in saltwater aquariums, carbonate ions begin to play a role. Alkalinity is the measure of the total acid binding capacity (all the anions which can bind with free H+) but is comprised mostly of carbonate hardness in freshwater systems. Thus, in practical freshwater usage, the terms carbonate hardness, acid binding, acid buffering capacity, and alkalinity are used interchangeably. In an aquarium, KH acts as a chemical buffering agent, helping to stabilize pH. KH is generaly referred to in degrees hardness and is expressed in CaCO3 equivalents just like GH. In simple terms, pH is determined by the negative log of the concentration of free hydrogen ions (H+) in the water. If you add a strong acid such as nitric acid to water, it completely dissociates into hydrogen ions (H+) and its "conjugate base" or "salt", NO3- or nitrate. The hydrogen ions freed in the reaction then increase the concentration of hydrogen ions and reduce the pH. Since nitric acid is the end product of the nitrogen cycle, this explains why aquarium pH tends to decrease and nitrates tend to increase over time. When the aquarium has some carbonate buffering in it, the bicarbonate ions will combine with the excess hydrogen ions to form carbonic acid (H2CO3) which then slowly breaks down into CO2 and water. Since the excess hydrogen ions are used in the reaction, the pH does not change very much. Over time, as the carbonate ions are used up, the buffering capacity will drop and larger pH changes will be noted. From this it is clear why aquariums with low KH seem unstable - as acid is produced by biological action, the KH is used up; when it is gone, the pH is free to drop rapidly as H+ ions are generated." The above is from thekrib.com
Mike S. has also written articles on this subject... I'll see if I can find the link...
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Drew
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