| Hello Philip and welcome!
You say there are no water pumps...only air stones. What kind of filtration plan do you have for the pond? Other than a mud pond that has extremely low stocking levels, we need filtration systems to handle the conversion of ammonia to nitrite to nitrate. And put push or pull through the filter sytem we need water pumps.
The alkalinity of the water will drop in a closed system. That is because the fish exhall carbon dioxide that becomes weak carbonic acid in the water. Rain water falling through the atmosphere also picks up cabron dioxide and delivers weak carbonic acid to the pond. So the alkalinity in the pond will try to counteract the acids and keep the pH steady. If the alkalinity is used up and not replaced (water changes, adding baking soda, adding limestone or oyster shell) the pH will slide do into the acid range (pH below 7). Eventually the water can get too acidic for the bacteria to convert ammonia-nitrite-nitrate. Then you can have toxic levels of ammonia.
So please tell us more about your pond size and volume, how you do water changes, water parametes (ammonia, nitrite, pH, KH or alkalinity). We will all help as we can from this side.
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Too much sanity may be madness and maddest of all is to see life as it is and not as it should be.
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